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Synthesis, Magnetic Properties, and Catalytic Properties of a Nickel(II)-Dependent Biomimetic of Metallohydrolases

A dinickel(II) complex of the ligand 1,3-bis(bis(pyridin-2-ylmethyl)amino)propan-2-ol (HL1) has been prepared and characterized to generate a functional model for nickel(II) phosphoesterase enzymes. The complex, [Ni(2)(L1)(μ-OAc)(H(2)O)(2)](ClO(4))(2)·H(2)O, was characterized by microanalysis, X-ray...

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Detalles Bibliográficos
Autores principales: Horn Jr., Adolfo, Englert, Daniel, Roberts, Asha E., Comba, Peter, Schenk, Gerhard, Krenske, Elizabeth H., Gahan, Lawrence R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6168013/
https://www.ncbi.nlm.nih.gov/pubmed/30320072
http://dx.doi.org/10.3389/fchem.2018.00441