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Why Is Water More Reactive Than Hydrogen in Photocatalytic CO(2) Conversion at Higher Pressures? Elucidation by Means of X-Ray Absorption Fine Structure and Gas Chromatography–Mass Spectrometry

Photocatalytic conversion of CO(2) into mainly methane using Pd/TiO(2) photocatalyst proceeded faster at 0.80 MPa using water rather than hydrogen as a reductant. The former reaction (CO(2) + water) consists of two steps: first, water photosplitting and second, the latter reaction (CO(2) + hydrogen)...

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Detalles Bibliográficos
Autores principales: Zhang, Hongwei, Izumi, Yasuo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6171473/
https://www.ncbi.nlm.nih.gov/pubmed/30320057
http://dx.doi.org/10.3389/fchem.2018.00408