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Why Is Water More Reactive Than Hydrogen in Photocatalytic CO(2) Conversion at Higher Pressures? Elucidation by Means of X-Ray Absorption Fine Structure and Gas Chromatography–Mass Spectrometry
Photocatalytic conversion of CO(2) into mainly methane using Pd/TiO(2) photocatalyst proceeded faster at 0.80 MPa using water rather than hydrogen as a reductant. The former reaction (CO(2) + water) consists of two steps: first, water photosplitting and second, the latter reaction (CO(2) + hydrogen)...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6171473/ https://www.ncbi.nlm.nih.gov/pubmed/30320057 http://dx.doi.org/10.3389/fchem.2018.00408 |