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Post‐Assembly Reactivity of N‐Aryl Iminoboronates: Reversible Radical Coupling and Unusual B−N Dynamic Covalent Chemistry

Post‐assembly reaction of a dynamic covalent iminoboronate system following addition of Cp(2)Co resulted in the formation of a series of new reductively coupled dianionic dimers via C−C bond formation. The dimers formed as a mixture of BN‐containing isomeric products: diastereomers rac (5) and meso...

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Detalles Bibliográficos
Autores principales: Keyzer, Evan N., Sava, Alexandru, Ronson, Tanya K., Nitschke, Jonathan R., McConnell, Anna J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6175077/
https://www.ncbi.nlm.nih.gov/pubmed/29972260
http://dx.doi.org/10.1002/chem.201802790