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Modular Functionalization of Arenes in a Triply Selective Sequence: Rapid C(sp(2)) and C(sp(3)) Coupling of C−Br, C−OTf, and C−Cl Bonds Enabled by a Single Palladium(I) Dimer

Full control over multiple competing coupling sites would enable straightforward access to densely functionalized compound libraries. Historically, the site selection in Pd(0)‐catalyzed functionalizations of poly(pseudo)halogenated arenes has been unpredictable, being dependent on the employed catal...

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Detalles Bibliográficos
Autores principales: Keaveney, Sinead T., Kundu, Gourab, Schoenebeck, Franziska
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6175235/
https://www.ncbi.nlm.nih.gov/pubmed/30091504
http://dx.doi.org/10.1002/anie.201808386