Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical Switching

The mechanism and selectivity of terminal alkyne coupling reactions promoted by rhodium(I) complexes of NHC‐based CNC pincer ligands have been investigated. Synthetic and kinetic experiments support E‐ and gem‐enyne formation through a common reaction sequence involving hydrometallation and rate‐det...

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Detalles Bibliográficos
Autores principales: Storey, Caroline M., Gyton, Matthew R., Andrew, Rhiann E., Chaplin, Adrian B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6175324/
https://www.ncbi.nlm.nih.gov/pubmed/30004163
http://dx.doi.org/10.1002/anie.201807028

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6175324/
https://www.ncbi.nlm.nih.gov/pubmed/30004163
http://dx.doi.org/10.1002/anie.201807028

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