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Synthesis, Characterization, and Functionalization of 1‐Boraphenalenes

1‐Boraphenalenes have been synthesized by reaction of BBr(3) with 1‐(aryl‐ethynyl)naphthalenes, 1‐ethynylnaphthalene, and 1‐(pent‐1‐yn‐1‐yl)naphthalene and they can be selectively functionalized at boron or carbon to form bench‐stable products. All of these 1‐boraphenalenes have LUMOs localized on t...

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Detalles Bibliográficos
Autores principales: Kahan, Rachel J., Crossley, Daniel L., Cid, Jessica, Radcliffe, James E., Ingleson, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6175385/
https://www.ncbi.nlm.nih.gov/pubmed/29750391
http://dx.doi.org/10.1002/anie.201803180