Investigation of solid-state photochemical nitro–nitrito linkage isomerization: crystal structures of trans-bis­(ethyl­enedi­amine)(iso­thio­cyanato)­nitritocobalt(III) salts: thio­cyanate, chloride monohydrate, and perchlorate–thio­cyanate­(0.75/0.25)

The reaction cavities of the nitro groups in the crystals of the title compounds, trans-[Co(NO(2))(NCS)(C(2)H(8)N(2))(2)]·X, X = SCN(−) (I), Cl(−)·H(2)O (II), and (ClO(4) (−))(0.75)(SCN(−))(0.25) (III), have been investigated, revealing that the geometry of the inter­molecular N—H⋯O hydrogen bonds i...

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Detalles Bibliográficos
Autores principales: Ohba, Shigeru, Tsuchimoto, Masanobu, Kurachi, Saeko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176456/
https://www.ncbi.nlm.nih.gov/pubmed/30319816
http://dx.doi.org/10.1107/S2056989018013634

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6176456/
https://www.ncbi.nlm.nih.gov/pubmed/30319816
http://dx.doi.org/10.1107/S2056989018013634

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