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Efficient catalytic alkyne metathesis with a fluoroalkoxy-supported ditungsten(III) complex
The molybdenum and tungsten complexes M(2)(OR)(6) (Mo2F6, M = Mo, R = C(CF(3))(2)Me; W2F3, M = W, R = OC(CF(3))Me(2)) were synthesized as bimetallic congeners of the highly active alkyne metathesis catalysts [MesC≡M{OC(CF(3))(n)Me(3−)(n)}] (MoF6, M = Mo, n = 2; WF3, M = W, n = 1; Mes = 2,4,6-trimeth...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6178283/ https://www.ncbi.nlm.nih.gov/pubmed/30344767 http://dx.doi.org/10.3762/bjoc.14.220 |