H(2)O(2) Oxidation by Fe(III)–OOH Intermediates and Its Effect on Catalytic Efficiency

[Image: see text] The oxidation of the C–H and C=C bonds of hydrocarbons with H(2)O(2) catalyzed by non-heme iron complexes with pentadentate ligands is widely accepted as involving a reactive Fe(IV)=O species such as [(N4Py)Fe(IV)=O](2+) formed by homolytic cleavage of the O–O bond of an Fe(III)–OO...

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Detalles Bibliográficos
Autores principales: Chen, Juan, Draksharapu, Apparao, Angelone, Davide, Unjaroen, Duenpen, Padamati, Sandeep K., Hage, Ronald, Swart, Marcel, Duboc, Carole, Browne, Wesley R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6179451/
https://www.ncbi.nlm.nih.gov/pubmed/30319886
http://dx.doi.org/10.1021/acscatal.8b02326

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6179451/
https://www.ncbi.nlm.nih.gov/pubmed/30319886
http://dx.doi.org/10.1021/acscatal.8b02326

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