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A soft phosphorus atom to “harden” an erbium(iii) single-ion magnet

Beyond the lanthanide organometallic single-ion magnet (SIM) (Cp*)Er(COT)(1) ([Cp*](–) = pentamethylcyclopentadienide; COT(2–) = cyclooctatetraenide) that has a good performance, we managed to replace one coordinated carbon atom on the [Cp*](–) ring by a soft phosphorus atom and obtained (Dsp)Er(COT...

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Detalles Bibliográficos
Autores principales: Chen, Shi-Ming, Xiong, Jin, Zhang, Yi-Quan, Yuan, Qiong, Wang, Bing-Wu, Gao, Song
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6180309/
https://www.ncbi.nlm.nih.gov/pubmed/30319754
http://dx.doi.org/10.1039/c8sc01626g