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A selenium-catalysed para-amination of phenols

Antioxidant enzyme glutathione peroxidase (GPx) decomposes hydroperoxides by utilizing the different redox chemistry of the selenium and sulfur. Here, we report a Se-catalysed para-amination of phenols while, in contrast, the reactions with sulfur donors are stoichiometric. A catalytic amount of phe...

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Detalles Bibliográficos
Autores principales: Yan, Dingyuan, Wang, Guoqiang, Xiong, Feng, Sun, Wei-Yin, Shi, Zhuangzhi, Lu, Yi, Li, Shuhua, Zhao, Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6191425/
https://www.ncbi.nlm.nih.gov/pubmed/30327477
http://dx.doi.org/10.1038/s41467-018-06763-4