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Benzoate Cyclometalation Enables Oxidative Addition of Haloarenes at a Ru(II) Center
[Image: see text] The first Ru(II)-catalyzed arylation of substrates without a directing group was recently developed. Remarkably, this process only worked in the presence of a benzoate additive, found to be crucial for the oxidative addition step at Ru(II). However, the exact mode of action of the...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6192667/ https://www.ncbi.nlm.nih.gov/pubmed/30134657 http://dx.doi.org/10.1021/jacs.8b08150 |