1-Oxo-2,2,6,6-tetramethylpiperidinium bromide converts α-H N,N-dialkylhydroxylamines to nitrones via a two-electron oxidation mechanism

Herein we provide experimental proof that 1-oxo-2,2,6,6-tetramethylpiperidinium bromide converts α-H N,N-dialkylhydroxylamines to nitrones via a two-electron oxidation mechanism. The reactions reported are rapid, proceed under mild conditions, and afford nitrones in excellent yields.

Detalles Bibliográficos
Autores principales: Stoyanovsky, Anastas D., Stoyanovsky, Detcho A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6193029/
https://www.ncbi.nlm.nih.gov/pubmed/30333514
http://dx.doi.org/10.1038/s41598-018-33639-w

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6193029/
https://www.ncbi.nlm.nih.gov/pubmed/30333514
http://dx.doi.org/10.1038/s41598-018-33639-w

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