Alternating oligo(o,p-phenylenes) via ruthenium catalyzed diol–diene benzannulation: orthogonality to cross-coupling enables de novo nanographene and PAH construction

Ruthenium(0) catalyzed diol–diene benzannulation is applied to the conversion of oligo(p-phenylene vinylenes) 2a–c, 5 and 6 to alternating oligo(o,p-phenylenes) 10a–c, 11–13. Orthogonality with respect to conventional palladium catalyzed biaryl cross-coupling permits construction of p-bromo-terminat...

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Detalles Bibliográficos
Autores principales: Kasun, Zachary A., Sato, Hiroki, Nie, Jing, Mori, Yasuyuki, Bender, Jon A., Roberts, Sean T., Krische, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6194800/
https://www.ncbi.nlm.nih.gov/pubmed/30429996
http://dx.doi.org/10.1039/c8sc03236j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6194800/
https://www.ncbi.nlm.nih.gov/pubmed/30429996
http://dx.doi.org/10.1039/c8sc03236j

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