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Alternating oligo(o,p-phenylenes) via ruthenium catalyzed diol–diene benzannulation: orthogonality to cross-coupling enables de novo nanographene and PAH construction

Ruthenium(0) catalyzed diol–diene benzannulation is applied to the conversion of oligo(p-phenylene vinylenes) 2a–c, 5 and 6 to alternating oligo(o,p-phenylenes) 10a–c, 11–13. Orthogonality with respect to conventional palladium catalyzed biaryl cross-coupling permits construction of p-bromo-terminat...

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Detalles Bibliográficos
Autores principales:	Kasun, Zachary A., Sato, Hiroki, Nie, Jing, Mori, Yasuyuki, Bender, Jon A., Roberts, Sean T., Krische, Michael J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6194800/ https://www.ncbi.nlm.nih.gov/pubmed/30429996 http://dx.doi.org/10.1039/c8sc03236j

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