Selective C–H halogenation over hydroxylation by non-heme iron(iv)-oxo

Non-heme iron based halogenase enzymes promote selective halogenation of the sp(3)-C–H bond through iron(iv)-oxo-halide active species. During halogenation, competitive hydroxylation can be prevented completely in enzymatic systems. However, synthetic iron(iv)-oxo-halide intermediates often result i...

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Detalles Bibliográficos
Autores principales: Rana, Sujoy, Biswas, Jyoti Prasad, Sen, Asmita, Clémancey, Martin, Blondin, Geneviève, Latour, Jean-Marc, Rajaraman, Gopalan, Maiti, Debabrata
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6194801/
https://www.ncbi.nlm.nih.gov/pubmed/30429994
http://dx.doi.org/10.1039/c8sc02053a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6194801/
https://www.ncbi.nlm.nih.gov/pubmed/30429994
http://dx.doi.org/10.1039/c8sc02053a

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