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Toward the Total Synthesis of Ryanodol via Oxidative Alkyne–1,3-Diketone Annulation: Construction of a Ryanoid Tetracycle
[Image: see text] A synthetic strategy conceived with the intent of establishing a novel approach to the de novo construction of ryanoids is described that is based on a recently developed metallacycle-mediated intramolecular oxidative alkyne–1,3-diketone coupling reaction. In short, a one-pot annul...
Autores principales: | Du, Kang, Kier, Matthew J., Rheingold, Arnold L., Micalizio, Glenn C. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2018
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6199674/ https://www.ncbi.nlm.nih.gov/pubmed/30264570 http://dx.doi.org/10.1021/acs.orglett.8b02767 |
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