Multinuclear iron–phenyl species in reactions of simple iron salts with PhMgBr: identification of Fe(4)(μ-Ph)(6)(THF)(4) as a key reactive species for cross-coupling catalysis

The first direct syntheses, structural characterizations, and reactivity studies of iron–phenyl species formed upon reaction of Fe(acac)(3) and PhMgBr in THF are presented. Reaction of Fe(acac)(3) with 4 equiv. PhMgBr in THF leads to the formation of [FePh(2)(μ-Ph)](2)(2–) at –80 °C, which can be st...

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Detalles Bibliográficos
Autores principales: Carpenter, Stephanie H., Baker, Tessa M., Muñoz, Salvador B., Brennessel, William W., Neidig, Michael L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6201819/
https://www.ncbi.nlm.nih.gov/pubmed/30429998
http://dx.doi.org/10.1039/c8sc02915f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6201819/
https://www.ncbi.nlm.nih.gov/pubmed/30429998
http://dx.doi.org/10.1039/c8sc02915f

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