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Multinuclear iron–phenyl species in reactions of simple iron salts with PhMgBr: identification of Fe(4)(μ-Ph)(6)(THF)(4) as a key reactive species for cross-coupling catalysis
The first direct syntheses, structural characterizations, and reactivity studies of iron–phenyl species formed upon reaction of Fe(acac)(3) and PhMgBr in THF are presented. Reaction of Fe(acac)(3) with 4 equiv. PhMgBr in THF leads to the formation of [FePh(2)(μ-Ph)](2)(2–) at –80 °C, which can be st...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6201819/ https://www.ncbi.nlm.nih.gov/pubmed/30429998 http://dx.doi.org/10.1039/c8sc02915f |