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Rapid and Quantitative De-tert-butylation for Poly(acrylic acid) Block Copolymers and Influence on Relaxation of Thermoassociated Transient Networks

[Image: see text] The synthesis of charged polymers often requires the polymerization of protected monomers, followed by a polymer-analogous reaction to the polyelectrolyte product. We present a mild, facile method to cleave tert-butyl groups from poly(tert-butyl acrylate) blocks that yields poly(ac...

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Detalles Bibliográficos
Autores principales: Filippov, Alexei D., van Hees, Ilse A., Fokkink, Remco, Voets, Ilja K., Kamperman, Marleen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6202630/
https://www.ncbi.nlm.nih.gov/pubmed/30405273
http://dx.doi.org/10.1021/acs.macromol.8b01440