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Reduction and Condensation of Aldehydes by the Isolated Cofactor of Nitrogenase
[Image: see text] Isolated nitrogenase cofactors can reduce CO, CN(–), and CO(2) to short-chain hydrocarbons in reactions driven by a strong reductant. Here, we use activity analyses and isotope labeling experiments to show that formaldehyde and acetaldehydes can be reduced as-is or reductively cond...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6202647/ https://www.ncbi.nlm.nih.gov/pubmed/30410981 http://dx.doi.org/10.1021/acscentsci.8b00553 |