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Reduction and Condensation of Aldehydes by the Isolated Cofactor of Nitrogenase

[Image: see text] Isolated nitrogenase cofactors can reduce CO, CN(–), and CO(2) to short-chain hydrocarbons in reactions driven by a strong reductant. Here, we use activity analyses and isotope labeling experiments to show that formaldehyde and acetaldehydes can be reduced as-is or reductively cond...

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Detalles Bibliográficos
Autores principales: Lee, Chi Chung, Hu, Yilin, Ribbe, Markus W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6202647/
https://www.ncbi.nlm.nih.gov/pubmed/30410981
http://dx.doi.org/10.1021/acscentsci.8b00553