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Ultrafast carbon monoxide photolysis and heme spin-crossover in myoglobin via nonadiabatic quantum dynamics

Light absorption of myoglobin triggers diatomic ligand photolysis and a spin crossover transition of iron(II) that initiate protein conformational change. The photolysis and spin crossover reactions happen concurrently on a femtosecond timescale. The microscopic origin of these reactions remains con...

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Detalles Bibliográficos
Autores principales: Falahati, Konstantin, Tamura, Hiroyuki, Burghardt, Irene, Huix-Rotllant, Miquel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6206034/
https://www.ncbi.nlm.nih.gov/pubmed/30374057
http://dx.doi.org/10.1038/s41467-018-06615-1