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The cumene/O(2) system: a very simple tool for the radical chain oxidation of some functional groups

Due to the relative stability of the cumyl radical, cumenes and α-methyl-styrenes are ideally structured to directly harvest the oxidizing reactivity of O(2) and initiate radical chain reactions in catalyst-free conditions. In the absence of additional substrates, these processes can lead to acetoph...

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Detalles Bibliográficos
Autores principales: Malekafzali, A., Malinovska, K., Patureau, F. W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6208464/
https://www.ncbi.nlm.nih.gov/pubmed/30450001
http://dx.doi.org/10.1039/c7nj01666b