The cumene/O(2) system: a very simple tool for the radical chain oxidation of some functional groups

Due to the relative stability of the cumyl radical, cumenes and α-methyl-styrenes are ideally structured to directly harvest the oxidizing reactivity of O(2) and initiate radical chain reactions in catalyst-free conditions. In the absence of additional substrates, these processes can lead to acetoph...

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Autores principales: Malekafzali, A., Malinovska, K., Patureau, F. W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6208464/
https://www.ncbi.nlm.nih.gov/pubmed/30450001
http://dx.doi.org/10.1039/c7nj01666b
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author Malekafzali, A.
Malinovska, K.
Patureau, F. W.
author_facet Malekafzali, A.
Malinovska, K.
Patureau, F. W.
author_sort Malekafzali, A.
collection PubMed
description Due to the relative stability of the cumyl radical, cumenes and α-methyl-styrenes are ideally structured to directly harvest the oxidizing reactivity of O(2) and initiate radical chain reactions in catalyst-free conditions. In the absence of additional substrates, these processes can lead to acetophenones. In the presence of substrates, the cumene oxidation process can be intercepted in various chain reactions, affording very simple protocols for functional group oxidation.
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spelling pubmed-62084642018-11-16 The cumene/O(2) system: a very simple tool for the radical chain oxidation of some functional groups Malekafzali, A. Malinovska, K. Patureau, F. W. New J Chem Chemistry Due to the relative stability of the cumyl radical, cumenes and α-methyl-styrenes are ideally structured to directly harvest the oxidizing reactivity of O(2) and initiate radical chain reactions in catalyst-free conditions. In the absence of additional substrates, these processes can lead to acetophenones. In the presence of substrates, the cumene oxidation process can be intercepted in various chain reactions, affording very simple protocols for functional group oxidation. Royal Society of Chemistry 2017-08-07 2017-06-30 /pmc/articles/PMC6208464/ /pubmed/30450001 http://dx.doi.org/10.1039/c7nj01666b Text en This journal is © The Royal Society of Chemistry 2017 https://creativecommons.org/licenses/by/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Malekafzali, A.
Malinovska, K.
Patureau, F. W.
The cumene/O(2) system: a very simple tool for the radical chain oxidation of some functional groups
title The cumene/O(2) system: a very simple tool for the radical chain oxidation of some functional groups
title_full The cumene/O(2) system: a very simple tool for the radical chain oxidation of some functional groups
title_fullStr The cumene/O(2) system: a very simple tool for the radical chain oxidation of some functional groups
title_full_unstemmed The cumene/O(2) system: a very simple tool for the radical chain oxidation of some functional groups
title_short The cumene/O(2) system: a very simple tool for the radical chain oxidation of some functional groups
title_sort cumene/o(2) system: a very simple tool for the radical chain oxidation of some functional groups
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6208464/
https://www.ncbi.nlm.nih.gov/pubmed/30450001
http://dx.doi.org/10.1039/c7nj01666b
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