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Chiral Control in Pentacoordinate Systems: The Case of Organosilicates
[Image: see text] Chirality at the central element of pentacoordinate systems can be controlled with two identical bidentate ligands. In such cases the topological Levi–Desargues graph for all the Berry pseudorotations (BPR, max. 20) reduces to interconnected inner and outer “circles” that represent...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6209177/ https://www.ncbi.nlm.nih.gov/pubmed/30277076 http://dx.doi.org/10.1021/acs.inorgchem.8b01861 |