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Chiral Control in Pentacoordinate Systems: The Case of Organosilicates

[Image: see text] Chirality at the central element of pentacoordinate systems can be controlled with two identical bidentate ligands. In such cases the topological Levi–Desargues graph for all the Berry pseudorotations (BPR, max. 20) reduces to interconnected inner and outer “circles” that represent...

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Detalles Bibliográficos
Autores principales:	van der Boon, Leon J. P., van Gelderen, Laurens, de Groot, Tim R., Lutz, Martin, Slootweg, J. Chris, Ehlers, Andreas W., Lammertsma, Koop
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2018
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6209177/ https://www.ncbi.nlm.nih.gov/pubmed/30277076 http://dx.doi.org/10.1021/acs.inorgchem.8b01861

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