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Direct oxygen isotope effect identifies the rate-determining step of electrocatalytic OER at an oxidic surface

Understanding the mechanism of water oxidation to dioxygen represents the bottleneck towards the design of efficient energy storage schemes based on water splitting. The investigation of kinetic isotope effects has long been established for mechanistic studies of various such reactions. However, so...

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Detalles Bibliográficos
Autores principales: Haschke, Sandra, Mader, Michael, Schlicht, Stefanie, Roberts, André M., Angeles-Boza, Alfredo M., Barth, Johannes A. C., Bachmann, Julien
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6212532/
https://www.ncbi.nlm.nih.gov/pubmed/30385759
http://dx.doi.org/10.1038/s41467-018-07031-1