Crystal structures of the [Ir(III){C(C(4)H(6)O(2))(dppm)-κ(3) P,C,O}(dppm)H](CF(3)O(3)S)(2) and [Ir(III){C(C(4)H(6)O(2))(dppm)-κ(2) P,C}(CO)(dppm)H](CF(3)O(3)S)(2) phosphorus ylide complexes, generated by a Wittig-type carbon–carbon coupling reaction of a carbodiphospho­rane PCP ligand system

The reaction of [Ir(III){C(dppm)(2)-κ(3) P,C,P′}ClH(NH(3)C(2))]Cl with ethyl diazo­acetate, a well known C=C coupling reagent, leads to the formation of a C=C unit, accompanied by N(2) abstraction, reorganization of a dppm subunit and, considered as a whole, to the transformation of the PCP pincer c...

Descripción completa

Detalles Bibliográficos
Autores principales: Schlapp-Hackl, Inge, Pauer, Bettina, Falschlunger, Christoph, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218904/
https://www.ncbi.nlm.nih.gov/pubmed/30443398
http://dx.doi.org/10.1107/S205698901801455X

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218904/
https://www.ncbi.nlm.nih.gov/pubmed/30443398
http://dx.doi.org/10.1107/S205698901801455X

Ejemplares similares