The first spontaneous resolution of a sulfoxide: Dianin’s compound analogue, (R)-4-(4-hy­droxy­phen­yl)-2,2,4-tri­methyl­thia­chroman-1-oxide

The title sulfoxide, C(18)H(20)O(2)S, was prepared by controlled oxidation of thia-Dianin’s compound using hydrogen peroxide in glacial acetic acid. On recrystallization from glacial acetic acid, it was found to form unsolvated, spontaneously resolved crystals, the initial crystal structure analysis...

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Detalles Bibliográficos
Autores principales: Gall, James H., White, J. Derek, MacNicol, David D., Frampton, Christopher S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218920/
https://www.ncbi.nlm.nih.gov/pubmed/30443396
http://dx.doi.org/10.1107/S2056989018014366

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218920/
https://www.ncbi.nlm.nih.gov/pubmed/30443396
http://dx.doi.org/10.1107/S2056989018014366

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