Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives

Selective creation of quaternary carbon centers has been a long-standing challenge in synthetic chemistry. We report here the chromium-catalyzed, para-selective formation of arylated quaternary carbon centers by alkylative reactions of benzamide derivatives with tertiary alkylmagnesium bromides at r...

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Detalles Bibliográficos
Autores principales: Liu, Pei, Chen, Changpeng, Cong, Xuefeng, Tang, Jinghua, Zeng, Xiaoming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6219510/
https://www.ncbi.nlm.nih.gov/pubmed/30401829
http://dx.doi.org/10.1038/s41467-018-07069-1

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6219510/
https://www.ncbi.nlm.nih.gov/pubmed/30401829
http://dx.doi.org/10.1038/s41467-018-07069-1

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