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Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives
Selective creation of quaternary carbon centers has been a long-standing challenge in synthetic chemistry. We report here the chromium-catalyzed, para-selective formation of arylated quaternary carbon centers by alkylative reactions of benzamide derivatives with tertiary alkylmagnesium bromides at r...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6219510/ https://www.ncbi.nlm.nih.gov/pubmed/30401829 http://dx.doi.org/10.1038/s41467-018-07069-1 |