Electronic chirality inversion of lanthanide complex induced by achiral molecules

A novel mechanism for chiroptical activity inversion based on the electronic structure of metal complexes without Λ- or Δ-type structure change was demonstrated spectroscopically and theoretically. To demonstrate the mechanism, a europium (Eu(III)) complex with chiral (+)-3-(trifluoroacetyl)camphor...

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Detalles Bibliográficos
Autores principales: Wada, Satoshi, Kitagawa, Yuichi, Nakanishi, Takayuki, Gon, Masayuki, Tanaka, Kazuo, Fushimi, Koji, Chujo, Yoshiki, Hasegawa, Yasuchika
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6219555/
https://www.ncbi.nlm.nih.gov/pubmed/30401813
http://dx.doi.org/10.1038/s41598-018-34790-0

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6219555/
https://www.ncbi.nlm.nih.gov/pubmed/30401813
http://dx.doi.org/10.1038/s41598-018-34790-0

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