Cargando…

Electronic chirality inversion of lanthanide complex induced by achiral molecules

A novel mechanism for chiroptical activity inversion based on the electronic structure of metal complexes without Λ- or Δ-type structure change was demonstrated spectroscopically and theoretically. To demonstrate the mechanism, a europium (Eu(III)) complex with chiral (+)-3-(trifluoroacetyl)camphor...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wada, Satoshi, Kitagawa, Yuichi, Nakanishi, Takayuki, Gon, Masayuki, Tanaka, Kazuo, Fushimi, Koji, Chujo, Yoshiki, Hasegawa, Yasuchika
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2018
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6219555/ https://www.ncbi.nlm.nih.gov/pubmed/30401813 http://dx.doi.org/10.1038/s41598-018-34790-0

Ejemplares similares

Chiral lanthanide lumino-glass for a circularly polarized light security device
por: Kitagawa, Yuichi, et al.
Publicado: (2020)

Chiral photochemistry of achiral molecules
por: Raucci, Umberto, et al.
Publicado: (2022)

Characteristic stacked structures and luminescent properties of dinuclear lanthanide complexes with pyrene units
por: Nakai, Takuma, et al.
Publicado: (2023)

Condensation and asymmetric amplification of chirality in achiral molecules adsorbed on an achiral surface
por: Liu, Huiru, et al.
Publicado: (2023)

Structural metamorphosis and photophysical properties of thermostable nano- and microcrystalline lanthanide polymer with flexible coordination chains
por: Nakanishi, Takayuki, et al.
Publicado: (2023)

Multi-level chirality in liquid crystals formed by achiral molecules
por: Salamończyk, Mirosław, et al.
Publicado: (2019)

Hyper-stable organo-Eu(III) luminophore under high temperature for photo-industrial application
por: Nakajima, Ayako, et al.
Publicado: (2016)

Stacked nanocarbon photosensitizer for efficient blue light excited Eu(III) emission
por: Kitagawa, Yuichi, et al.
Publicado: (2020)

Asymmetric Assembly of Chiral Lanthanide(III) Tetranuclear Cluster Complexes Using Achiral Mixed Ligands: Single-molecule Magnet Behavior and Magnetic Entropy Change
por: Liu, Cai-Ming, et al.
Publicado: (2022)

Preparation of photonic molecular trains via soft-crystal polymerization of lanthanide complexes
por: Ferreira da Rosa, Pedro Paulo, et al.
Publicado: (2022)

Lanthanide MOFs for inducing molecular chirality of achiral stilbazolium with strong circularly polarized luminescence and efficient energy transfer for color tuning
por: Zeng, Min, et al.
Publicado: (2020)

Critical Role of Energy Transfer Between Terbium Ions for Suppression of Back Energy Transfer in Nonanuclear Terbium Clusters
por: Omagari, Shun, et al.
Publicado: (2016)

Achiral Zeolites as Reaction Media for Chiral Photochemistry
por: Ramamurthy, Vaidhyanathan
Publicado: (2019)

Chirality in the Solid State: Chiral Crystal Structures in Chiral and Achiral Space Groups
por: Fecher, Gerhard H., et al.
Publicado: (2022)

Bright sky-blue fluorescence with high color purity: assembly of luminescent diphenyl-anthracene lutetium-based coordination polymer
por: Kitagawa, Yuichi, et al.
Publicado: (2021)

Right handed chiral superstructures from achiral molecules: self-assembly with a twist
por: Anuradha, A, et al.
Publicado: (2015)

Steric and Electronic Control of Chiral Eu(III) Complexes for Effective Circularly Polarized Luminescence
por: Kitagawa, Yuichi, et al.
Publicado: (2020)

Emergence of single-molecular chirality from achiral reactants
por: Steendam, René R. E., et al.
Publicado: (2014)

Supramolecular Copolymerization of Bichromophoric Chiral and Achiral Perylenediimide Dyes
por: Yonezawa, Shumpei, et al.
Publicado: (2021)

Improvement in aqueous solubility of achiral symmetric cyclofenil by modification to a chiral asymmetric analog
por: Morimoto, Junki, et al.
Publicado: (2021)

Engineering Achiral Liquid Crystalline Polymers for Chiral Self-Recovery
por: Miao, Tengfei, et al.
Publicado: (2021)

Chiral emergence in multistep hierarchical assembly of achiral conjugated polymers
por: Park, Kyung Sun, et al.
Publicado: (2022)

Assembly of planar chiral superlattices from achiral building blocks
por: Cheng, Zhihua, et al.
Publicado: (2022)

Observation of the Chiral and Achiral Hexatic Phases of Self-assembled Micellar polymers
por: Pal, Antara, et al.
Publicado: (2016)

Application of Carbon Nanotubes in Chiral and Achiral Separations of Pharmaceuticals, Biologics and Chemicals
por: Hemasa, Ayman L., et al.
Publicado: (2017)

Template-assisted self-assembly of achiral plasmonic nanoparticles into chiral structures
por: Vila-Liarte, David, et al.
Publicado: (2021)

Self-recovery of chiral microphase separation in an achiral diblock copolymer system
por: Miao, Tengfei, et al.
Publicado: (2023)

Two-ring chirality generated by the alignment of two achiral phenylacetylene macrocycles
por: Katoono, Ryo, et al.
Publicado: (2023)

Achiral Molecular Recognition of Aromatic Position Isomers by Polysaccharide-Based CSPs in Relation to Chiral Recognition
por: Shibata, Tohru, et al.
Publicado: (2016)

Heliconical smectic phases formed by achiral molecules
por: Abberley, Jordan P., et al.
Publicado: (2018)

Organic linkers control the thermosensitivity of the emission intensities from Tb(iii) and Eu(iii) in a chameleon polymer
por: Hatanaka, Miho, et al.
Publicado: (2017)

Induction of Circularly Polarized Electroluminescence from an Achiral Light-Emitting Polymer via a Chiral Small-Molecule Dopant
por: Yang, Ying, et al.
Publicado: (2013)

Spontaneous emergence of chirality in achiral lyotropic chromonic liquid crystals confined to cylinders
por: Nayani, Karthik, et al.
Publicado: (2015)

Environmentally Sustainable Achiral and Chiral Chromatographic Analysis of Amino Acids in Food Supplements
por: Varfaj, Ina, et al.
Publicado: (2022)

Achiral Molecular Recognition of Substituted Aniline Position Isomers by Crown Ether Type Chiral Stationary Phase
por: Ohnishi, Atsushi, et al.
Publicado: (2021)

Addendum: Heliconical smectic phases formed by achiral molecules
por: Abberley, Jordan P., et al.
Publicado: (2018)

Ferroelectric metallomesogens composed of achiral spin crossover molecules
por: Akiyoshi, Ryohei, et al.
Publicado: (2019)

Synthesis of racemic and chiral BEDT-TTF derivatives possessing hydroxy groups and their achiral and chiral charge transfer complexes
por: Krivickas, Sara Jane, et al.
Publicado: (2015)

Chiroptical Performances in Self-Assembled Hierarchical Nanosegregated Chiral Intermediate Phases Composed of Two Different Achiral Bent-Core Molecules
por: Lee, Jae-Jin, et al.
Publicado: (2022)

An achiral ferromagnetic/chiral antiferromagnetic bilayer system leading to controllable size and density of skyrmions
por: Morvan, F. J., et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_v8oiod2kuf7vvip35shp3q15ts