Mechanochemical Activation of Zinc and Application to Negishi Cross‐Coupling

A form independent activation of zinc, concomitant generation of organozinc species and engagement in a Negishi cross‐coupling reaction via mechanochemical methods is reported. The reported method exhibits a broad substrate scope for both C(sp(3))–C(sp(2)) and C(sp(2))–C(sp(2)) couplings and is tole...

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Detalles Bibliográficos
Autores principales: Cao, Qun, Howard, Joseph L., Wheatley, Emilie, Browne, Duncan L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6220771/
https://www.ncbi.nlm.nih.gov/pubmed/30015403
http://dx.doi.org/10.1002/anie.201806480

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6220771/
https://www.ncbi.nlm.nih.gov/pubmed/30015403
http://dx.doi.org/10.1002/anie.201806480

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