Synthesis of 3‐Amino‐1‐benzothiophene‐1,1‐diones by Alkyne Directed Hydroarylation and 1/N→3/C‐Sulfonyl Migration

A completely regioselective and highly stereoselective palladium‐catalyzed intramolecular hydroarylation of arenesulfonyl ynamines to benzothiazoles was developed. The presence of an electron‐withdrawing group on the triple bond of the sulfonyl ynamine was crucial for the success of the reaction and...

Descripción completa

Detalles Bibliográficos
Autores principales: Bernar, Ivan, Blanco‐Ania, Daniel, Stok, Sophie J., Sotorríos, Lia, Gómez‐Bengoa, Enrique, Rutjes, Floris P. J. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6220774/
https://www.ncbi.nlm.nih.gov/pubmed/30443160
http://dx.doi.org/10.1002/ejoc.201801062

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6220774/
https://www.ncbi.nlm.nih.gov/pubmed/30443160
http://dx.doi.org/10.1002/ejoc.201801062

Ejemplares similares