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The High‐Pressure Oxide Tb(3)O(5) and its Non‐Centrosymmetric Low‐Temperature Polymorph–A Comprehensive Study

In this article, the first thoroughly characterized mixed‐valent binary rare earth oxide synthesized under high‐pressure/high‐temperature conditions, and its low‐temperature polymorph are reported. Crystalline HT‐HP‐Tb(3)O(5) has been prepared from an equimolar mixture of Tb(4)O(7) and Tb(2)O(3) und...

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Detalles Bibliográficos
Autores principales: Glätzle, Matthias, Janka, Oliver, Svitlyk, Volodymyr, Chernyshov, Dmitry, Bartsch, Manfred, Zacharias, Helmut, Pöttgen, Rainer, Huppertz, Hubert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6220859/
https://www.ncbi.nlm.nih.gov/pubmed/30133951
http://dx.doi.org/10.1002/chem.201804006