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Stereoselective Synthesis of Mechanically Planar Chiral Rotaxanes

Chiral interlocked molecules in which the mechanical bond provides the sole stereogenic unit are typically produced with no control over the mechanical stereochemistry. Here we report a stereoselective approach to mechanically planar chiral rotaxanes in up to 98:2 d.r. using a readily available α‐am...

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Detalles Bibliográficos
Autores principales: Jinks, Michael A., de Juan, Alberto, Denis, Mathieu, Fletcher, Catherine J., Galli, Marzia, Jamieson, Ellen M. G., Modicom, Florian, Zhang, Zhihui, Goldup, Stephen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6220991/
https://www.ncbi.nlm.nih.gov/pubmed/30253008
http://dx.doi.org/10.1002/anie.201808990