Accelerated Ru–Cu Trinuclear Cooperative C−H Bond Functionalization of Carbazoles: A Kinetic and Computational Investigation

The mechanism of a trinuclear cooperative dehydrogenative C−N bond‐forming reaction is investigated in this work, which avoids the use of chelate‐assisting directing groups. Two new highly efficient Ru/Cu co‐catalyzed systems were identified, allowing orders of magnitude greater TOFs than the previo...

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Detalles Bibliográficos
Autores principales: Jones, Alexander W., Rank, Christian K., Becker, Yanik, Malchau, Christian, Funes‐Ardoiz, Ignacio, Maseras, Feliu, Patureau, Frederic W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6221041/
https://www.ncbi.nlm.nih.gov/pubmed/29928784
http://dx.doi.org/10.1002/chem.201802886

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6221041/
https://www.ncbi.nlm.nih.gov/pubmed/29928784
http://dx.doi.org/10.1002/chem.201802886

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