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Photoinduced Remote Functionalization of Amides and Amines Using Electrophilic Nitrogen Radicals

The selective functionalization of C(sp(3))−H bonds at distal positions to functional groups is a challenging task in synthetic chemistry. Reported here is a photoinduced radical cascade strategy for the divergent functionalization of amides and protected amines. The process is based on the oxidativ...

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Detalles Bibliográficos
Autores principales: Morcillo, Sara P., Dauncey, Elizabeth M., Kim, Ji Hye, Douglas, James J., Sheikh, Nadeem S., Leonori, Daniele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6221136/
https://www.ncbi.nlm.nih.gov/pubmed/30074300
http://dx.doi.org/10.1002/anie.201807941