Unusual Polycyclic Fused Product by Oxidative Enzymatic Dimerisation of 5-methylpyrogallol Catalysed by Horseradish Peroxidase/H(2)O(2)

During investigations on the peroxidase-catalysed oxidation of polyhydroxylated monoaromatic substrates such as 5-methylpyrogallol, we observed a spectacular dimerisation proceeding by dearomatisation in contrast with most common reaction patterns involving phenolics oxidation and dimerization. A te...

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Detalles Bibliográficos
Autores principales: Bouges, Hélène, Calabro, Kevin, Thomas, Olivier P., Antoniotti, Sylvain
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6222440/
https://www.ncbi.nlm.nih.gov/pubmed/30322056
http://dx.doi.org/10.3390/molecules23102619

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6222440/
https://www.ncbi.nlm.nih.gov/pubmed/30322056
http://dx.doi.org/10.3390/molecules23102619

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