Regio- and Stereoselective Allylindation of Alkynes Using InBr(3) and Allylic Silanes: Synthesis, Characterization, and Application of 1,4-Dienylindiums toward Skipped Dienes

Regioselective anti-allylindation of alkynes was achieved using InBr(3) and allylic silanes. Various types of alkynes and allylic silanes were applicable to the present allylindation. This sequential process used the generated 1,4-dienylindiums to establish novel synthetic methods for skipped dienes...

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Detalles Bibliográficos
Autores principales: Nishimoto, Yoshihiro, Yi, Junyi, Takata, Tatsuaki, Baba, Akio, Yasuda, Makoto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6222668/
https://www.ncbi.nlm.nih.gov/pubmed/30060532
http://dx.doi.org/10.3390/molecules23081884

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6222668/
https://www.ncbi.nlm.nih.gov/pubmed/30060532
http://dx.doi.org/10.3390/molecules23081884

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