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Biosynthesis of Grandione: An Example of Tandem Hetero Diels-Alder/Retro-Claisen Rearrangement Reaction?

Mechanistic theoretical studies about the feasibility of the traditional proposed mechanism of formation for icetexane diterpene dimer grandione were assessed using density functional method at the M06-2X/6-31G(d,p) level of theory. Bulk water solvent effects were taken into account implicitly using...

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Detalles Bibliográficos
Autores principales: Quijano-Quiñones, Ramiro F., Castro-Segura, Carolina S., Mena-Rejón, Gonzalo J., Quesadas-Rojas, Mariana, Cáceres-Castillo, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6222908/
https://www.ncbi.nlm.nih.gov/pubmed/30274324
http://dx.doi.org/10.3390/molecules23102505