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Light-controlled switching of the spin state of iron(III)
Controlled switching of the spin state of transition metal ions, particularly of Fe(II) and Fe(III), is a prerequisite to achieve selectivity, efficiency, and catalysis in a number of metalloenzymes. Here we report on an iron(III) porphyrin with a photochromic axial ligand which, upon irradiation wi...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6232099/ https://www.ncbi.nlm.nih.gov/pubmed/30420598 http://dx.doi.org/10.1038/s41467-018-07023-1 |