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Light-controlled switching of the spin state of iron(III)

Controlled switching of the spin state of transition metal ions, particularly of Fe(II) and Fe(III), is a prerequisite to achieve selectivity, efficiency, and catalysis in a number of metalloenzymes. Here we report on an iron(III) porphyrin with a photochromic axial ligand which, upon irradiation wi...

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Detalles Bibliográficos
Autores principales: Shankar, Sreejith, Peters, Morten, Steinborn, Kim, Krahwinkel, Bahne, Sönnichsen, Frank D., Grote, Dirk, Sander, Wolfram, Lohmiller, Thomas, Rüdiger, Olaf, Herges, Rainer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6232099/
https://www.ncbi.nlm.nih.gov/pubmed/30420598
http://dx.doi.org/10.1038/s41467-018-07023-1