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Synthesis of (±)-trans-2,5-Diisopropylborolane

The cyclic hydroboration of 2,7-dimethyl-2,6-octadiene (6) was studied. It was found that the stereochemical outcome of the reaction was dependent upon the solvent, temperature, time and the nature of the borane reagent. Pure racemic trans-2,5-diisopropylborolane (14) was isolated following selectiv...

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Detalles Bibliográficos
Autores principales: Laschober, Gerhard, Zorzi, Massimo, Hodgetts, Kevin J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236339/
http://dx.doi.org/10.3390/60300244