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Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents‡

Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH(−) -form) vinyl silanes are converted into epoxysilanes.

Detalles Bibliográficos
Autores principales: Domann, Silvie, Sourkouni-Argirusi, Georgia, Merayo, Nuria, Schönberger, Andreas, Kirschning, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236340/
http://dx.doi.org/10.3390/60100061