Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents‡

Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH(−) -form) vinyl silanes are converted into epoxysilanes.

Detalles Bibliográficos
Autores principales: Domann, Silvie, Sourkouni-Argirusi, Georgia, Merayo, Nuria, Schönberger, Andreas, Kirschning, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236340/
http://dx.doi.org/10.3390/60100061
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author Domann, Silvie
Sourkouni-Argirusi, Georgia
Merayo, Nuria
Schönberger, Andreas
Kirschning, Andreas
author_facet Domann, Silvie
Sourkouni-Argirusi, Georgia
Merayo, Nuria
Schönberger, Andreas
Kirschning, Andreas
author_sort Domann, Silvie
collection PubMed
description Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH(−) -form) vinyl silanes are converted into epoxysilanes.
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spelling pubmed-62363402018-11-20 Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents‡ Domann, Silvie Sourkouni-Argirusi, Georgia Merayo, Nuria Schönberger, Andreas Kirschning, Andreas Molecules Article Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH(−) -form) vinyl silanes are converted into epoxysilanes. MDPI 2001-01-16 /pmc/articles/PMC6236340/ http://dx.doi.org/10.3390/60100061 Text en © 2001 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Domann, Silvie
Sourkouni-Argirusi, Georgia
Merayo, Nuria
Schönberger, Andreas
Kirschning, Andreas
Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents‡
title Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents‡
title_full Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents‡
title_fullStr Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents‡
title_full_unstemmed Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents‡
title_short Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents‡
title_sort cohalogenation of allyl and vinylsilanes using polymer-bound haloate(i)-reagents‡
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236340/
http://dx.doi.org/10.3390/60100061
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