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Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents‡
Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH(−) -form) vinyl silanes are converted into epoxysilanes.
Autores principales: | Domann, Silvie, Sourkouni-Argirusi, Georgia, Merayo, Nuria, Schönberger, Andreas, Kirschning, Andreas |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2001
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236340/ http://dx.doi.org/10.3390/60100061 |
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