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Generation and Cycloaddition of o-Quinodimethane in Aqueous Medium

o-Quinodimethane can be generated from α,α'-dihalo-o-xylenes using zinc in aqueous solution. In the presence of activated dienophiles cycloadducts can be obtained directly. Catalysis with tris-triphenylphosphine ruthenium(II) dichloride reduces side reactions such as reduction and polymerisatio...

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Detalles Bibliográficos
Autores principales: Bieber, Lothar W., da Silva, Margarete F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236402/
http://dx.doi.org/10.3390/60500472