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Generation and Cycloaddition of o-Quinodimethane in Aqueous Medium
o-Quinodimethane can be generated from α,α'-dihalo-o-xylenes using zinc in aqueous solution. In the presence of activated dienophiles cycloadducts can be obtained directly. Catalysis with tris-triphenylphosphine ruthenium(II) dichloride reduces side reactions such as reduction and polymerisatio...
Autores principales: | Bieber, Lothar W., da Silva, Margarete F. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2001
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236402/ http://dx.doi.org/10.3390/60500472 |
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